3 papers
cond-mat.mtrl-sci2005
An organometallic chimie douce approach to new Re(x)W(1-x)O3 phases
Christian Helbig, Rudolf Herrmann, Franz Mayr +5
Re(x)W(1-x)O3.H2O and Re(x)W(1-x)O3 phases are prepared by a new organometallic chimie douce concept employing the organometallic precursor methyltrioxorhenium.
physics.chem-ph2005
Valence Shell Charge Concentrations at Pentacoordinate d0 Transition Metal Centers: Non-VSEPR Structures of Me2NbCl3 and Me3NbCl2
G. Sean McGrady, Arne Haaland, Hans Peter Verne +5
The molecular structures of the monomeric, pentacoordinated ethylchloroniobium(V) compounds Me3NbCl2 and Me2NbCl3 have been determined by gas electron diffraction (GED)and Density…
cond-mat.mtrl-sci2005
Possible Localization Behavior of the Inherent Conducting Polymer (CH)ReO
E. --W. Scheidt, R. Miller, Ch. Helbig +5
Polymeric methyltrioxorhenium (poly-MTO) represents the first example of an inherent conducting organometallic oxide. It adopts the structural motives and transport properties of s…