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20172026
most citedHighly Accurate Prediction of Core Spectra of Molecules at Density Functional Theory Cost: Attaining sub eV Error from a Restricted Open-Shell Kohn-Sham Approach

151 citations · 435 across the 22 of their papers we have counts for

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Showing 2020 · physics.chem-phShow all

5 papers · 2 filters

physics.chem-ph2020★ 19 cited

Too big, too small or just right? A benchmark assessment of density functional theory for predicting the spatial extent of the electron density of small chemical systems

Diptarka Hait, Yu Hsuan Liang, Martin Head-Gordon

Multipole moments are the first order responses of the energy to spatial derivatives of the electric field strength. The quality of density functional theory (DFT) prediction of mo…

physics.chem-ph2020

Third order Møller-Plesset theory made more useful? The role of density functional theory orbitals

Adam Rettig, Diptarka Hait, Luke W. Bertels +1

The practical utility of Møller-Plesset (MP) perturbation theory is severely constrained by the use of Hartree-Fock (HF) orbitals. It has recently been shown that use of regularize…

physics.chem-ph2020

The Ground State Electronic Energy of Benzene

Janus J. Eriksen, Tyler A. Anderson, J. Emiliano Deustua +21

We report on the findings of a blind challenge devoted to determining the frozen-core, full configuration interaction (FCI) ground state energy of the benzene molecule in a standar…

physics.chem-ph2020★ 48 cited

Accurate prediction of core-level spectra of radicals at density functional theory cost via square gradient minimization and recoupling of mixed configurations

Diptarka Hait, Eric A. Haugen, Zheyue Yang +3

State-specific orbital optimized approaches are more accurate at predicting core-level spectra than traditional linear-response protocols, but their utility had been restricted on…

physics.chem-ph2020★ 151 cited

Highly Accurate Prediction of Core Spectra of Molecules at Density Functional Theory Cost: Attaining sub eV Error from a Restricted Open-Shell Kohn-Sham Approach

Diptarka Hait, Martin Head-Gordon

We present the use of the recently developed Square Gradient Minimization (SGM) algorithm for excited state orbital optimization, to obtain spin-pure Restricted Open-Shell Kohn-Sha…