Pinning down electron correlations in RaF via spectroscopy of excited states and high-accuracy relativistic quantum chemistry

M. Athanasakis-Kaklamanakis, S. G. Wilkins, L. V. Skripnikov +53

We report the spectroscopy of the 14 lowest excited electronic states in the radioactive molecule radium monofluoride (RaF). The observed excitation energies are compared with full…