4 papers
Intrinsic Matching Frustration in Fluctuating Finite Systems
Leonid Rubinovich, Micha Polak
We formulate intrinsic matching frustration (IMF), a fluctuation-induced, kinetics-independent reduction in the mean capacity permitted by a prescribed matching rule. For complemen…
Modeling nanoconfined reaction kinetics: Alternative methodology incorporating equilibrium extent fluctuations
Leonid Rubinovich, Micha Polak
This study reveals that Equilibrium Constant Differential Equations (ECDE) for nanoconfined reactions derived recently in the frameworks of statistical mechanics are useful in mode…
Chemical Reactions under Nanoconfinement: Unravelling Equilibrium Constant Equations
Leonid Rubinovich, Micha Polak
Equilibrium Constant Differential Equations (ECDE) are derived for several nanoconfined elemental bimolecular reactions in the frameworks of statistical mechanics and the ideal gas…
Computationally efficient analytic representation of relativistic transition matrix elements in the Lamb shift calculations for hydrogenic atoms
J. Seke, A. V. Soldatov, M. Polak +1
By using the plane-wave expansion for the electromagnetic-field vector potential, transition matrix elements between the relativistic bound and unbound states of hydrogenic atoms w…