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cond-mat.mtrl-sci2001
Single-Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn-Teller Isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]
Colette Boskovic, Maren Pink, John C. Huffman +2
The Mn12Ac single-molecule magnet has been converted for the first time into a form that contains non-carboxylate ligands. Reaction of Mn12Ac with diphenylphosphinic acid converts…
cond-mat.mtrl-sci2001
Single-Molecule Magnets: Preparation and Properties of Mixed-Carboxylate Complexes [Mn12O12(O2CR)8(O2CR')8(H2O)4]
Monica Soler, Pau Artus, Kirsten Folting +3
Methods are reported for the preparation of mixed-carboxylate versions of the [Mn12O12(O2CR)16(H2O)4] family of single-molecule magnets (SMMs). [Mn12O12(O2CCHCl2)8(O2CCH2But)8(H2O)…