activity
20182023
most citedSpatially-resolved Fluorescence-detected Two-dimensional Electronic Spectroscopy Probes Varying Electronic Couplings in Photosynthetic Bacteria

137 citations · 192 across the 9 of their papers we have counts for

collaborators

9 papers

physics.chem-ph2023

Low and High Frequency Vibrations Synergistically Enhance Singlet Exciton Fission Through Robust Vibronic Resonances

Atandrita Bhattacharyya, Amitav Sahu, Sanjoy Patra +1

Singlet exciton fission (SEF) is initiated by ultrafast internal conversion of a singlet exciton into a correlated triplet pair (TT)1. The `reaction coordinates' for ultrafast SEF…

physics.chem-ph2023

Coherence Transfer and Destructive Interference in Two-Dimensional Coherence Maps

Amitav Sahu, Vivek Tiwari

Coherence maps (CMs) in multidimensional spectroscopy report total interference of all quantum coherent pathways. Detailed understanding of how this interference manifests spectros…

physics.chem-ph2022

Rapid Scan White Light Pump-Probe Spectroscopy with 100 kHz Shot-to-Shot Detection

Vivek N. Bhat, Asha S. Thomas, Vivek Tiwari

We demonstrate a femtosecond pump-probe spectrometer which utilizes a white light supercontinuum as input, and relies on mutual synchronization of acousto-optical chopper, pump-pro…

physics.chem-ph2022

High-sensitivity Fluorescence-Detected Multidimensional Electronic Spectroscopy Through Continuous Pump-probe Delay Scan

Amitav Sahu, Vivek N. Bhat, Sanjoy Patra +1

Background-free fluorescence detection in multidimensional electronic spectroscopy promises high sensitivity compared to conventional approaches. Here we explore the sensitivity li…

physics.chem-ph2022

Vibronic Resonance Along Effective Modes Mediates Selective Energy Transfer in Excitonically Coupled Aggregates

Sanjoy Patra, Vivek Tiwari

We recently proposed effective normal modes for excitonically coupled aggregates which exactly transform the energy transfer Hamiltonian into a sum of one-dimensional Hamiltonians…

physics.chem-ph2020★ 8 cited

Trap Mediated Energy Transport via Vibronic Resonance

Sanjoy Patra, Amitav Sahu, Vivek Tiwari

Controlling energy transfer through vibronic resonance is an interesting possibility. Exact treatment of non-adiabatic vibronic coupling is necessary to fully capture its role in d…

physics.chem-ph2020★ 1 cited

Resonant Vibrational-Electronic Coupling between Photosynthetic Excitons is Inadequately Described by Reduced Basis Sets

Amitav Sahu, Jo Sony Kurian, Vivek Tiwari

Vibrational-electronic (vibronic) resonance and its role in energy and charge transfer has been experimentally and theoretically investigated in several photosynthetic proteins. Us…

physics.chem-ph2018★ 46 cited

Strongly Coupled Bacteriochlorophyll Dyad Studied Using Two-dimensional Phase-modulated Fluorescence-detected Electronic Spectroscopy

Vivek Tiwari, Yassel Acosta Matutes, Zhanqian Yu +6

Fluorescence-detected two-dimensional electronic spectroscopy (F-2DES) projects the third-order non-linear polarization in a system as an excited electronic state population which…

physics.chem-ph2018★ 137 cited

Spatially-resolved Fluorescence-detected Two-dimensional Electronic Spectroscopy Probes Varying Electronic Couplings in Photosynthetic Bacteria

Vivek Tiwari, Yassel Acosta-Matutes, Alastair T. Gardiner +2

We present a variation of two-dimensional electronic spectroscopy that is capable of mapping spatially-varying differences in electronic couplings using a correlated map of excitat…