activity
20202022
most citedBivariational Principle for an Antisymmetrized Product of Nonorthogonal Geminals Appropriate for Strong Electron Correlation

3 citations · 4 across the 6 of their papers we have counts for

collaborators

7 papers

physics.chem-ph20223 cited

Bivariational Principle for an Antisymmetrized Product of Nonorthogonal Geminals Appropriate for Strong Electron Correlation

Paul A. Johnson, Paul W. Ayers, Stijn De Baerdemacker +2

We develop a bivariational principle for an antisymmetric product of nonorthogonal geminals. Special cases reduce to the antisymmetric product of strongly-orthogonal geminals (APSG…

physics.chem-ph20221 cited

Near-exact treatment of seniority-zero ground and excited states with a Richardson-Gaudin mean-field

Charles-Émile Fecteau, Samuel Cloutier, Jean-David Moisset +4

Eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian, Richardson-Gaudin (RG) states, are used as a variational wavefunction Ansatz for strongly-correlated electronic s…

physics.chem-ph2021

Perturbative corrections for Hartree-Fock-like Algebraic Bethe Ansatz analogue

Jean-David Moisset, Laurie Carrier, Paul A. Johnson

Rayleigh Schrödinger perturbation theory corrections are developed for an algebraic Bethe ansatz of individual electrons. Numerical results are ambiguous and would need either an o…

physics.chem-ph2020

Transition density matrices of Richardson-Gaudin states

Paul A. Johnson, Hubert Fortin, Samuel Cloutier +1

Recently, ground state eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian, Richardson-Gaudin (RG) states, have been employed as a wavefunction ansatz for strong corr…

physics.chem-ph2020

Richardson-Gaudin geminal wavefunctions in a Slater determinant basis

Charles-Émile Fecteau, Frédéric Berthiaume, Meriem Khalfoun +1

Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable appro…

physics.chem-ph2020

Reduced density matrices of Richardson-Gaudin states in the Gaudin algebra basis

Charles-Émile Fecteau, Hubert Fortin, Samuel Cloutier +1

Eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian have recently been employed as a variational wavefunction ansatz in quantum chemistry. This wavefunction is a mean…