most citedNear-exact treatment of seniority-zero ground and excited states with a Richardson-Gaudin mean-field

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5 papers

physics.chem-ph20221 cited

Near-exact treatment of seniority-zero ground and excited states with a Richardson-Gaudin mean-field

Charles-Émile Fecteau, Samuel Cloutier, Jean-David Moisset +4

Eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian, Richardson-Gaudin (RG) states, are used as a variational wavefunction Ansatz for strongly-correlated electronic s…

physics.chem-ph2020

Transition density matrices of Richardson-Gaudin states

Paul A. Johnson, Hubert Fortin, Samuel Cloutier +1

Recently, ground state eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian, Richardson-Gaudin (RG) states, have been employed as a wavefunction ansatz for strong corr…

physics.chem-ph2020

Richardson-Gaudin geminal wavefunctions in a Slater determinant basis

Charles-Émile Fecteau, Frédéric Berthiaume, Meriem Khalfoun +1

Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable appro…

physics.chem-ph2020

Reduced density matrices of Richardson-Gaudin states in the Gaudin algebra basis

Charles-Émile Fecteau, Hubert Fortin, Samuel Cloutier +1

Eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian have recently been employed as a variational wavefunction ansatz in quantum chemistry. This wavefunction is a mean…

physics.chem-ph2020

Richardson-Gaudin mean-field for strong correlation in quantum chemistry

P. A. Johnson, C. -É. Fecteau, F. Berthiaume +8

Ground state eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian are employed as a wavefunction ansatz to model strong electron correlation in quantum chemistry. This…