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physics.chem-ph2020
Born-Oppenheimer approximation in optical cavities: from success to breakdown
Csaba Fábri, Gábor J. Halász, Lorenz S. Cederbaum +1
The coupling of a molecule and a cavity induces non-adiabaticity in the molecule which makes the description of its dynamics complicated. For polyatomic molecules, reduced-dimensio…
physics.chem-ph2020
Striking light-induced nonadiabatic fingerprint in the low-energy vibronic spectra of polyatomic molecules
Csaba Fábri, Benjamin Lasorne, Gábor J. Halász +2
Nonadiabaticity, i.e., the effect of mixing electronic states by nuclear motion, is a central phenomenon in molecular science. The strongest nonadiabatic effects arise due to the p…