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physics.chem-ph2006
Steric effects in the dynamics of electrolytes at large applied voltages: II. Modified Poisson-Nernst-Planck equations
Mustafa Sabri Kilic, Martin Z. Bazant, Armand Ajdari
In situations involving large potentials or surface charges, the Poisson Boltzman(PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This ha…
physics.chem-ph2006
Steric effects in the dynamics of electrolytes at large applied voltages: I. Double-layer charging
Mustafa Sabri Kilic, Martin Z. Bazant, Armand Ajdari
The classical Poisson-Boltzmann (PB) theory of electrolytes assumes a dilute solution of point charges with mean-field electrostatic forces. Even for very dilute solutions, however…