4 papers
A Fluctuation Theory of Liquid-Phase Solutions: Shear Viscosity
Yury A. Budkov, Nikolai N. Kalikin, Petr E. Brandyshev
Accurately describing liquids and their mixtures beyond equilibrium remains a significant challenge in modern chemical physics and physical chemistry, especially regarding the calc…
Thermomechanical Approach to Calculating Mechanical Stresses in Inhomogeneous Fluids and Its Applications to Ionic Fluids
Yu. A. Budkov, N. N. Kalikin, P. E. Brandyshev
This extended article presents a thermomechanical approach for calculating the stress tensor from the thermodynamic potential of inhomogeneous fluids and some applications to ionic…
Modified Debye-Hückel-Onsager Theory for Electrical Conductivity in Aqueous Electrolyte Solutions. Account of Ionic Charge Nonlocality
N. N. Kalikin, Yu. A. Budkov
The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-Hückel-Onsager theory to provide a detailed description of the electrical conductivi…
Surface Tension of Aqueous Electrolyte Solutions. A Thermomechanical Approach
Yury A. Budkov, Nikolai N. Kalikin, Petr E. Brandyshev
We determine the surface tension of aqueous electrolyte solutions in contact with non-polar dielectric media using a thermomechanical approach, which involves deriving the stress t…