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20102020
most citedThe density matrix renormalization group for ab initio quantum chemistry

307 citations · 1.3k across the 22 of their papers we have counts for

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Showing 2014Show all

7 papers · 1 filter

math-ph2014★ 5 cited

The Dicke model as the contraction limit of a pseudo-deformed Richardson-Gaudin model

Pieter W. Claeys, Stijn De Baerdemacker, Mario Van Raemdonck +1

The Dicke model is derived in the contraction limit of a pseudo-deformation of the quasispin algebra in the su(2)-based Richardson-Gaudin models. Likewise, the integrability of the…

physics.chem-ph2014★ 307 cited

The density matrix renormalization group for ab initio quantum chemistry

Sebastian Wouters, Dimitri Van Neck

During the past 15 years, the density matrix renormalization group (DMRG) has become increasingly important for ab initio quantum chemistry. Its underlying wavefunction ansatz, the…

cond-mat.str-el2014★ 107 cited

Projected seniority-two orbital optimization of the Antisymmetric Product of one-reference orbital Geminal

Katharina Boguslawski, Paweł Tecmer, Peter A. Limacher +5

We present a new, non-variational orbital-optimization scheme for the Antisymmetric Product of one-reference orbital Geminal wave function. Our approach is motivated by the observa…

cond-mat.str-el2014★ 29 cited

Projector quantum Monte Carlo with matrix product states

Sebastian Wouters, Brecht Verstichel, Dimitri Van Neck +1

We marry tensor network states (TNS) and projector quantum Monte Carlo (PMC) to overcome the high computational scaling of TNS and the sign problem of PMC. Using TNS as trial wavef…

cond-mat.str-el2014★ 42 cited

Exact solution of the pairing Hamiltonian by deforming the pairing algebra

Mario Van Raemdonck, Stijn De Baerdemacker, Dimitri Van Neck

The present paper makes a connection between collective bosonic states and the exact solutions of the pairing Hamiltonian. This makes it possible to investigate the ef…

cond-mat.str-el2014★ 190 cited

CheMPS2: a free open-source spin-adapted implementation of the density matrix renormalization group for ab initio quantum chemistry

Sebastian Wouters, Ward Poelmans, Paul W. Ayers +1

The density matrix renormalization group (DMRG) has become an indispensable numerical tool to find exact eigenstates of finite-size quantum systems with strong correlation. In the…