activity
20162026
most citedMolecular polaritonics: Chemical Dynamics under strong Light-Matter Coupling

203 citations · 728 across the 48 of their papers we have counts for

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Showing 2023 · physics.chem-phShow all

9 papers · 2 filters

physics.chem-ph2023★ 1 cited

Total Angular Momentum Conservation in Ehrenfest Dynamics with a Truncated Basis of Adiabatic States

Zhen Tao, Xuezhi Bian, Yanze Wu +3

We show that standard Ehrenfest dynamics does not conserve linear and angular momentum when using a basis of truncated adiabatic states. However, we also show that previously propo…

physics.chem-ph2023

Linear and Angular Momentum Conservation in Surface Hopping Methods

Yanze Wu, Jonathan Rawlinson, Robert G. Littlejohn +1

We demonstrate that, for systems with spin-orbit coupling and an odd number of electrons, the standard fewest switches surface hopping (FSSH) algorithm does not conserve the total…

physics.chem-ph2023

Kubo-Anderson theory of polariton lineshape

Clàudia Climent, Joseph E. Subotnik, Abraham Nitzan

We apply the Kubo-Anderson stochastic theory of molecular spectral lineshape to the case of polaritons formed in the collective strong coupling regime. We investigate both the fast…

physics.chem-ph2023

On the nature of polariton transport in a Fabry-Perot Cavity

Zeyu Zhou, Hsing-Ta Chen, Maxim Sukharev +2

Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons poss…

physics.chem-ph2023

Surface Hopping, Electron Translation Factors, Electron Rotation Factors, Momentum Conservation, and Size Consistency

Vishikh Athavale, Xuezhi Bian, Zhen Tao +5

For a system without spin-orbit coupling, the (i) nuclear plus electronic linear momentum and (ii) nuclear plus orbital electronic angular momentum are good quantum numbers. Thus,…

physics.chem-ph2023★ 28 cited

Total Angular Momentum Conservation in Ab Initio Born-Oppenheimer Molecular Dynamics

Xuezhi Bian, Zhen Tao, Yanze Wu +3

We prove both analytically and numerically that the total angular momentum of a molecular system undergoing adiabatic Born-Oppenheimer dynamics is conserved only when pseudo-magnet…