Overlapping resonances in the control of intramolecular vibrational redistribution
arXiv:quant-ph/0703263 · doi:10.1063/1.2710791
Abstract
Coherent control of bound state processes via the interfering overlapping resonances scenario [Christopher et al., J. Chem. Phys. 123, 064313 (2006)] is developed to control intramolecular vibrational redistribution (IVR). The approach is applied to the flow of population between bonds in a model of chaotic OCS vibrational dynamics, showing the ability to significantly alter the extent and rate of IVR by varying quantum interference contributions.
10 pages, 7 figures