Helium energy levels including corrections
arXiv:physics/0610122 · doi:10.1103/PhysRevA.74.062510
Abstract
The correction to energy is expressed in terms of an effective Hamiltonian for an arbitrary state of helium. Numerical calculations are performed for levels, and the previous result for the centroid is corrected. While the resulting theoretical predictions for the ionization energy are in moderate agreement with experimental values for , , and states, they are in significant disagreement for the singlet state .
11 pages, with erratum submitted to Phys. Rev. A (2007)