Ordinary, extraordinary, and normal surface transitions: extraordinary-normal equivalence and simple explanation of singularities
arXiv:cond-mat/9402077 · doi:10.1103/PhysRevB.50.3894
Abstract
With simple, exact arguments we show that the surface magnetization at the extraordinary and normal transitions and the surface energy density at the ordinary, extraordinary, and normal transitions of semi-infinite -dimensional Ising systems have leading thermal singularities , with the same critical exponent and amplitude ratio as the bulk free energy . The derivation is carried out in three steps: (i) By tracing out the surface spins, the semi-infinite Ising model with supercritical surface enhancement and vanishing surface magnetic field is mapped exactly onto a semi-infinite Ising model with subcritical surface enhancement, a nonzero surface field, and irrelevant additional surface interactions. This establishes the equivalence of the extraordinary () and normal () transitions. (ii) The magnetization at the interface of an infinite system with uniform temperature and a nonzero magnetic field in the half-space only is shown to be proportional to . (iii) The energy density at the interface of an infinite system with temperatures and in the half-spaces and and no magnetic field is shown to be proportional to .
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