-NMR of Isolated Li Implanted into a Thin Copper Film
arXiv:cond-mat/0701002 · doi:10.1103/PhysRevB.75.073405
Abstract
Depth-controlled -NMR was used to study highly spin-polarized Li in a Cu film of thickness 100 nm deposited onto a MgO substrate. The positive Knight Shifts and spin relaxation data show that Li occupies two sites at low temperatures, assigned to be the substitutional () and octahedral () interstitial sites. Between 50 to 100 K, there is a site change from to . The temperature dependence of the Knight shifts and spin-lattice relaxation rates at high temperatures, i.e. when all the Li are in the site, is consistent with the Korringa Law for a simple metal.
Accepted for publication in Phys. Rev. B