Dielectric properties and lattice dynamics of Ca-doped K${}_{0.95}$Li${}_{0.05}$TaO${}_3$

Abstract

Relaxor behavior and lattice dynamics have been studied for a single crystal of K${}_{1-x}$Li${}_x$TaO${}_3$ $(x=0.05)$, where a small amount of a Ca impurity ($\sim 15$~ppm) was incorporated. The dielectric measurements revealed Debye-like relaxations with Arrhenius activation energies of 80 and 240 meV that are assigned to Li${}^{+}$ dipoles and the Li${}^{+}$-Li${}^{+}$ dipolar pairs, respectively. In the neutron scattering results, diffuse scattering ridges appear around the nuclear Bragg peaks below $\sim 150$ K and phonon line broadening features start to appear at even higher temperatures suggesting that polar nano-regions (PNR's) start to form at these temperatures. These results are supported by the dielectric data that reveal relaxor behavior starting at $\sim 200$ K on cooling. From analyses of the diffuse intensities, the displacements include a uniform phase shift of all of the atoms in addition to the atomic displacements corresponding to a polarization vector of the transverse optic soft ferroelectric mode, a finding that is analogous to that in the prototypical relaxor material Pb(Mg${}_{1/3}$Nb${}_{2/3}$)O${}_3$.

13 pages, 12 figures

References in corpus (8)

• Neutron Diffuse Scattering from Polar Nanoregions in the Relaxor Pb(Mg1/3Nb2/3)O3
• Soft Mode Dynamics Above and Below the Burns Temperature in the Relaxor Pb(Mg_1/3Nb_2/3)O_3
• Ferroelectric Ordering in the Relaxor Pb(Mg1/3Nb2/3)O3 as Evidenced by Low-Temperature Phonon Anomalies
• Universal Static and Dynamic Properties of the Structural Transition in Pb(Zn1/3Nb2/3)O3
• Dynamical effects of the nanometer-sized polarized domains in Pb(Zn1/3Nb2/3)O3
• Damped Soft Phonons and Diffuse Scattering in 40PMN-60PT
• Strong Influence of the diffuse component on the lattice dynamics in Pb(Mg${}_{1/3}$Nb${}_{2/3}$)O${}_3$
• The Energetics of Li Off-Centering in K${}_{1-x}$Li${}_x$TaO${}_3$; First Principles Calculations

Cited by in corpus (5)

• A reassessment of the Burns temperature and its relationship to the diffuse scattering, lattice dynamics, and thermal expansion in the relaxor PMN
• Soft phonon columns on the edge of the Brillouin zone in the relaxor PbMg1/3Nb2/3O3
• Response of polar nanoregions in 68%Pb(Mg1/3Nb2/3)O3-32%PbTiO3 to a [001] electric field
• The effect of local dipole moments on the structure and lattice dynamics of K0.98Li0.02TaO3
• Fluctuating defects in the incipient relaxor K${}_{1-x}$Li${}_x$TaO${}_3$ (x=0.02)