Phase segregation on the nanoscale in Na2C60

Abstract

Na2C60 is believed to be an electron-hole counterpart of the Mott-Jahn--Teller insulator A4C60 salts. We present a study of infrared, ESR, NMR spectroscopy, X-ray diffraction, chemical composition and neutron scattering on this compound. Our spectroscopic results at room temperature can be reconciled in a picture of segregated, separate regions of the size 3--10 nm. We observe a significant insulating C60 phase and at least two more phases, one of which we assign to metallic Na3C60. The separation disappears on heating by jump diffusion of the sodium ions, which we followed by neutron scattering. Above ~460 K we see infrared spectroscopic evidence of a Jahn--Teller distorted (C60)2- anion.

9 pages, 7 figures, submitted to Phys. Rev. B v2 and v3: replaced Fig. 7. (only cosmetic changes), v3: corrected Ref. 29, v4: changed text in Experimental section, changed colors in Figs. 1,2,3,4 (accepted version in journal)

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• The High-Flux Backscattering Spectrometer at the NIST Center for Neutron Research
• Metal-Insulator Transitions in Degenerate Hubbard Models and A${}_x$C${}_{60}$
• Non magnetic molecular Jahn-Teller Mott insulators
• In-Situ Infrared Transmission Study of Rb- and K-Doped Fullerenes
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• Static and dynamic Jahn-Teller effect in the alkali metal fulleride salts A4C60 (A = K, Rb, Cs)
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• Ordered low-temperature structure in K4C60 detected by infrared spectroscopy

Cited by in corpus (2)

• Multipurpose High Frequency Electron Spin Resonance Spectrometer for Condensed Matter Research
• Electronic and ionic conductivities in superionic Li${}_4$C${}_{60}$