paper

Microscopic Approach to Magnetism and Superconductivity of -Electron Systems with Filled Skutterudite Structure

arXiv:cond-mat/0504052 · doi:10.1143/JPSJ.74.1275

Abstract

In order to gain a deep insight into -electron properties of filled skutterudite compounds from a microscopic viewpoint, we investigate the multiorbital Anderson model including Coulomb interactions, spin-orbit coupling, and crystalline electric field effect. For each case of =113, where is the number of electrons per rare-earth ion, the model is analyzed by using the numerical renormalization group (NRG) method to evaluate magnetic susceptibility and entropy of electron. In order to make further step to construct a simplified model which can be treated even in a periodic system, we also analyze the Anderson model constructed based on the - coupling scheme by using the NRG method. Then, we construct an orbital degenerate Hubbard model based on the - coupling scheme to investigate the mechanism of superconductivity of filled skutterudites. In the 2-site model, we carefully evaluate the superconducting pair susceptibility for the case of =2 and find that the susceptibility for off-site Cooper pair is clearly enhanced only in a transition region in which the singlet and triplet ground states are interchanged.

14 pages, 11 figures, Typeset with jpsj2.cls

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