Neutron scattering study of the vibrations in vitreous silica and germania

Abstract

The incoherent approximation for the determination of the vibrational density of states of glasses from inelastic neutron or x-ray scattering data is extended to treat the coherent scattering. The method is applied to new room temperature measurements of vitreous silica and germania on the thermal time-of-flight spectrometer IN4 at the High Flux Reactor in Grenoble. The inelastic dynamic structure factor at the boson peak turns out to be reasonably well described in terms of a mixture of rotation and translation of practically undistorted SiO4 or GeO4 tetrahedra. The translational component exceeds the expectation of the Debye model by a factor of two. A possible relation of this excess to the phonon shift and broadening observed in x-ray Brillouin scattering experiments is discussed.

13 pages, 13 figures, 39 references

References in corpus (3)

• Glass-specific behavior in the damping of acoustic-like vibrations
• Vibrations and Relaxations in a Soft Sphere Glass: Boson Peak and Structure Factors
• The vibrational dynamics of vitreous silica: Classical force fields vs. first-principles

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