Exact results on spin dynamics and multiple quantum dynamics in alternating spin-1/2 chains with XY-Hamiltonian at high temperatures

Abstract

We extend the picture of a transfer of nuclear spin-1/2 polarization along a homogeneous one-dimensional chain with the XY-Hamiltonian to the inhomogeneous chain with alternating nearest neighbour couplings and alternating Larmor frequencies. To this end, we calculate exactly the spectrum of the spin-1/2 XY-Hamiltonian of the alternating chain with an odd number of sites. The exact spectrum of the XY-Hamiltonian is also applied to study the multiple quantum (MQ) NMR dynamics of the alternating spin-1/2 chain. MQ NMR spectra are shown to have the MQ coherences of zero and $\pm$ second orders just as in the case of a homogeneous chain. The intensities of the MQ coherences are calculated.

10 pages, 4 figures

References in corpus (2)

• Quantum Dynamical Echoes in the Spin 'Diffusion' in Mesoscopic Systems
• A solvable model of a random spin-1/2 XY chain

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