Crystal Nucleation of Colloidal Suspensions under Shear
arXiv:cond-mat/0406237 · doi:10.1103/PhysRevLett.93.068303
Abstract
We use Brownian Dynamics simulations in combination with the umbrella sampling technique to study the effect of shear flow on homogeneous crystal nucleation. We find that a homogeneous shear rate leads to a significant suppression of the crystal nucleation rate and to an increase of the size of the critical nucleus. A simple, phenomenological extension of classical nucleation theory accounts for these observations. The orientation of the crystal nucleus is tilted with respect to the shear direction.
4 pages, 3 figures, Submitted to Phys. Rev. Lett
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