The alpha to gamma transition in Ce: a theoretical view from optical spectroscopy
arXiv:cond-mat/0403086 · doi:10.1103/PhysRevLett.94.036401
Abstract
Using a novel approach to calculate optical properties of strongly correlated systems, we address the old question of the physical origin of the alpha to gamma transition in Ce. We find that the Kondo collapse model describes the optical data better than the Mott transition picture. Our results compare well with existing thin--film experiments. We predict the full temperature dependence of the optical spectra and find the development of a pseudogap around 0.6 eV in the vicinity of the alpha to gamma phase transition.
arXiv comment4 pages, 5 figures
References in corpus (8)
- Linear-response theory and lattice dynamics: a muffin-tin orbital approach
- The Cerium volume collapse: Results from the LDA+DMFT approach
- Anderson impurity model at finite Coulomb interaction U: generalized Non-crossing Approximation
- Thermodynamic and spectral properties of compressed Ce calculated by the merger of the local density approximation and dynamical mean field theory
- Volume-Collapse Transitions in the Rare Earth Metals
- The spectral and magnetic properties of - and -Ce from the Dynamical Mean-Field Theory and Local Density Approximation
- The role of the lattice in the phase transition of Ce: a high pressure neutron and x-ray diffraction study
- Infrared and optical spectroscopy of alpha and gamma-phase Ce
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