Spatially heterogeneous dynamics and dynamic facilitation in a model of viscous silica
arXiv:cond-mat/0402427 · doi:10.1103/PhysRevLett.92.255901
Abstract
Performing molecular dynamics simulations, we find that the structural relaxation dynamics of viscous silica, the prototype of a strong glass former, are spatially heterogeneous and cannot be understood as a statistical bond breaking process. Further, we show that high particle mobility predominantly propagates continuously through the melt, supporting the concept of dynamic facilitation emphasized in recent theoretical work.
arXiv comment4 pages, 4 figures
References in corpus (13)
- Dynamical heterogeneities in a supercooled Lennard-Jones liquid
- String-like Clusters and Cooperative Motion in a Model Glass-Forming Liquid
- Cooling rate effects in amorphous Silica: A Computer Simulation Study
- Spatial Correlations of Mobility and Immobility in a Glassforming Lennard-Jones Liquid
- Geometrical explanation and scaling of dynamical heterogeneities in glass forming systems
- Static and Dynamic Properties of a Viscous Silica Melt Molecular Dynamics Computer Simulations
- Fragile-to-strong transition and polyamorphism in the energy landscape of liquid silica
- Coarse-grained microscopic model of glass formers
- Crossover to Potential Energy Landscape Dominated Dynamics in a Model Glass-forming Liquid
- Connection between Adam-Gibbs Theory and Spatially Heterogeneous Dynamics
- The relaxation dynamics of a viscous silica melt: II The intermediate scattering functions
- Particle rearrangements during transitions between local minima of the potential energy landscape of a supercooled Lennard-Jones liquid
- The Dynamics of Supercooled Silica: Acoustic modes and Boson peak
Cited by in corpus (46)
- Dynamics on the Way to Forming Glass: Bubbles in Space-time
- Spontaneous and induced dynamic fluctuations in glass-formers I: General results and dependence on ensemble and dynamics
- Excitations are localized and relaxation is hierarchical in glass-forming liquids
- Direct measurements of growing amorphous order and non-monotonic dynamic correlations in a colloidal glass-former
- Relaxation and physical aging in network glasses: a review
- Thirty milliseconds in the life of a supercooled liquid
- Modern computational studies of the glass transition
- Dynamical Exchanges in Facilitated Models of Supercooled liquids
- Correlation between Fragility and the Arrhenius Crossover Phenomenon in Metallic, Molecular, and Network Liquids
- Heterogeneity and growing lengthscales in the dynamics of kinetically constrained lattice gases in two dimensions
- Growing Dynamical Facilitation on Approaching the Random Pinning Colloidal Glass Transition
- Temperature dependence of spatially heterogeneous dynamics in a model of viscous silica
- Heterogeneous relaxation dynamics in amorphous materials under cyclic loading
- Finite size effects in the dynamics of glass-forming liquids
- Microscopic origin of excess wings in relaxation spectra of supercooled liquids
- Structural and dynamical heterogeneity in a glass forming liquid
- The Origin of the Fragile-to-Strong Crossover in Liquid Silica as Expressed by its Potential Energy Landscape
- Dynamic heterogeneity and non-Gaussian behavior in a model supercooled liquid
- Constrained dynamics of localized excitations causes a non-equilibrium phase transition in an atomistic model of glass formers
- Dynamic heterogeneities above and below the mode-coupling temperature. Evidence of a dynamic crossover
- Revisiting the slow dynamics of a silica melt using Monte Carlo simulations
- Renormalization group study of a kinetically constrained model for strong glasses
- Deconstructing the glass transition through critical experiments on colloids
- Percolation of Immobile Domains in Supercooled Thin Polymeric Films
- Manifestations of Dynamical Facilitation in Glassy Materials
- Dynamical facilitation governs glassy dynamics in suspensions of colloidal ellipsoids
- Conformational and Structural Relaxations of Poly(ethylene oxide) and Poly(propylene oxide) Melts: Molecular Dynamics Study of Spatial Heterogeneity, Cooperativity, and Correlated Forward-Backward Motion
- Comparative classical and ab initio Molecular Dynamics study of molten and glassy germanium dioxide
- Fragile-to-strong transition in liquid silica
- Dynamics of liquid silica as explained by properties of the potential energy landscape
- Excess wings and asymmetric relaxation spectra in a facilitated trap model
- The Origin of the Decoupling of Oxygen and Silicon Dynamics in Liquid Silica as Expressed by its Potential Energy Landscape
- Self-Organized Criticality Below The Glass Transition
- Structural signatures of mobility on intermediate time scales in a supercooled fluid
- Direct numerical analysis of dynamic facilitation in glass-forming liquids
- Folding time dependence of the motions of a molecular motor diluted inside an amorphous medium
- Linking dynamical heterogeneity to static amorphous order
- Reduced strength and extent of dynamic heterogeneity in a strong glass former as compared to fragile glass formers
- Collective relaxation dynamics in a three-dimensional lattice glass model
- Enhanced diffusion in finite-size simulations of a fragile diatomic glass former
- Connecting microscopic simulations with kinetically constrained models of glasses
- Effective Trap-like Activated Dynamics in a Continuous Landscape
- Competing Relaxation Channels in Continuously Polydisperse Fluids: A Mode-Coupling Study
- How do packing defects modify the cooperative motions in supercooled liquids ?
- Structural (dis)order and dynamic propensity in a mildly undercooled glass-forming liquid: Spatial correlations and the role of crystalline environments
- Universal Scaling in the Aging of the Strong Glass Former SiO