paper

The field theoretic derivation of the contact value theorem in planar geometries and its modification by the Casimir effect

arXiv:cond-mat/0309028 · doi:10.1103/PhysRevE.68.061106

Abstract

The contact value theorem for Coulomb gases in planar or film-like geometries is derived using a Hamiltonian field theoretic representation of the system. The case where the film is enclosed by a material of different dielectric constant to that of the film is shown to contain an additional Casimir-like term which is generated by fluctuations of the electric potential about its mean-field value.

Link between Sine-Gordon and Coulomb gas pressures via subtraction of self interaction terms included. Discussion of results within Debye-Huckel approximation included. Added references

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