Liquid Crystal-Solid Interface Structure at the Antiferroelectric-Ferroelectric Phase Transition
arXiv:cond-mat/0302158 · doi:10.1103/PhysRevE.66.061709
Abstract
Total Internal Reflection (TIR) is used to probe the molecular organization at the surface of a tilted chiral smectic liquid crystal at temperatures in the vicinity of the bulk antiferroelectric-ferroelectric phase transition. Data are interpreted using an exact analytical solution of a real model for ferroelectric order at the surface. In the mixture T3, ferroelectric surface order is expelled with the bulk ferroelectric-antiferroelectric transition. The conditions for ferroelectric order at the surface of an antiferroelectric bulk are presented.