Entropy Driven Dimerization in a One-Dimensional Spin-Orbital Model
arXiv:cond-mat/0212368 · doi:10.1103/PhysRevB.67.100408
Abstract
We study a new version of the one-dimensional spin-orbital model with spins S=1 relevant to cubic vanadates. At small Hund's coupling J_H we discover dimerization in a pure electronic system solely due to a dynamical spin-orbital coupling. Above a critical value J_H, a uniform ferromagnetic state is stabilized at zero temperature. More surprisingly, we observe a temperature driven dimerization of the ferrochain, which occurs due to a large entropy released by dimer states. This dynamical dimerization seems to be the mechanism driving the peculiar intermediate phase of YVO_3.
5 pages, 4 figures