MgB2 single crystals: high pressure growth and anisotropic properties

Abstract

Single crystals of MgB2 with a size up to 1.5x0.9x0.2 mm3 have been grown with a high pressure cubic anvil technique. The crystal growth process is very peculiar and involves an intermediate nitride, namely MgNB9. Single crystals of BN and MgB2 grow simultaneously by a peritectic decomposition of MgNB9. Magnetic measurements in fields of 1-5 Oe show sharp transitions to the superconducting state at 37-38.6 K with width of ~0.5 K. The high quality of the crystals allowed the accurate determination of magnetic, transport and optical properties as well as scanning tunnelling spectroscopy (STS) and decoration studies. Investigations of crystals with torque magnetometry show that Hc2//c is very low (24 kOe at 15 K), while Hc2//ab increases up to 140 kOe at 15 K. The upper critical field anisotropy gamma = Hc2//ab/ Hc2//c was found to be temperature dependent (decreasing from 6 at 15 K to 2.8 at 35 K). The effective anisotropy gamma_eff, as calculated from reversible torque data near Tc, is field dependent (increasing roughly linearly from 2 in zero field to 3.7 in 10 kOe). The temperature and field dependence of the anisotropy can be related to the double gap structure of MgB2 with a large two-dimensional gap and small three-dimensional gap, the latter being rapidly suppressed in a magnetic field. Torque magnetometry investigations show a pronounced peak effect, indicating an order-disorder transition of vortex matter. Decoration experiments and STS visualise a hexagonal vortex lattice. STS spectra evidence two gaps (3 meV/6 meV) with direction dependent weight. Magneto-optic investigations with H//c show a clear signature of the smaller of the two gaps, disappearing in fields higher than Hc2//c.

17 pages pdf only, 15 figures integrated (higher resolution photographs available on request); submitted to Supercond. Sci. Technol. (Proceedings of Boromag conference)

References in corpus (18)

• Superconductivity of metallic boron in MgB_2
• Beyond Eliashberg superconductivity in MgB2: anharmonicity, two-phonon scattering, and multiple gaps
• Temperature and field dependence of the anisotropy of MgB2
• Vortex Imaging in the pi-Band of Magnesium Diboride
• Single crystal MgB2 with anisotropic superconducting properties
• Thermodynamics of the Mg-B system: Implications for the deposition of MgB2 thin films
• Growth, structure analysis and anisotropic superconducting properties of MgB2 single crystals
• Thermal conductivity of single crystalline MgB_2
• Mixed state properties of superconducting MgB2 single crystals
• Exponential Temperature Dependence of Penetration Depth in Single Crystal MgB_2
• Superconducting properties of well-shaped MgB2 single crystal
• Peak effect in single crystal MgB${}_2$ superconductor for $\mathbf{H}\parallel c$-axis
• Josephson effect in MgB_2 break junctions
• Temperature-dependent $H_{c2}$ anisotropy in MgB${}_2$ as inferred from measurements on polycrystals
• Bonding Nature in MgB2
• Superconducting anisotropy and evidence for intrinsic pinning in single crystalline MgB${}_2$
• Optical and Thermal-Transport Properties of an Inhomogeneous d-Wave Superconductor
• Magneto-optical reflectivity of superconducting MgB2 single crystals

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