Pressure-induced phase transitions of halogen-bridged binuclear metal complexes R_4[Pt_2(P_2O_5H_2)_4X]nH_2O
arXiv:cond-mat/0107128 · doi:10.1103/PhysRevB.64.140102
Abstract
Recent contrasting observations for halogen (X)-bridged binuclear platinum complexes R_4[Pt_2(P_2O_5H_2)_4X]nH_2O, that is, pressure-induced Peierls and reverse Peierls instabilities, are explained by finite-temperature Hartree-Fock calculations. It is demonstrated that increasing pressure transforms the initial charge-polarization state into a charge-density-wave state at high temperatures, whereas the charge-density-wave state oppositely declines with increasing pressure at low temperatures. We further predict that higher-pressure experiments should reveal successive phase transitions around room temperature.
5 pages, 4 figures embedded, to be published in Phys. Rev. B 64, September 1 (2001) Rapid Commun
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