Critical Dynamics of Gelation

Abstract

Shear relaxation and dynamic density fluctuations are studied within a Rouse model, generalized to include the effects of permanent random crosslinks. We derive an exact correspondence between the static shear viscosity and the resistance of a random resistor network. This relation allows us to compute the static shear viscosity exactly for uncorrelated crosslinks. For more general percolation models, which are amenable to a scaling description, it yields the scaling relation $k=\ddot{I}•-{\hat{I}}^2$ for the critical exponent of the shear viscosity. Here ${\hat{I}}^2$ is the thermal exponent for the gel fraction and $\ddot{I}•$ is the crossover exponent of the resistor network. The results on the shear viscosity are also used in deriving upper and lower bounds on the incoherent scattering function in the long-time limit, thereby corroborating previous results.

34 pages, 2 figures (revtex, amssymb); revised version (minor changes)