Aromatic Hydrocarbons, Diamonds, and Fullerenes in Interstellar Space: Puzzles to be Solved by Laboratory and Theoretical Astrochemistry
arXiv:astro-ph/0010138 · doi:10.1016/S1386-1425(00)00433-9
Abstract
New research is presented, and previous research is reviewed, on the emission and absorption of interstellar aromatic hydrocarbons. Emission from aromatic hydrocarbons dominate the mid-infrared emission of many galaxies, including our own Milky Way galaxy. Only recently have aromatic hydrocarbons been observed in absorption in the interstellar medium, along lines of sight with high column densities of interstellar gas and dust. Much work on interstellar aromatics has been done, with astronomical observations and laboratory and theoretical astrochemistry. In many cases the predictions of laboratory and theoretical work are confirmed by astronomical observations, but in other cases clear discrepancies exist which provide problems to be solved by a combination of astronomical observations, laboratory studies, and theoretical studies. The emphasis of this paper will be on current outstanding puzzles concerning aromatic hydrocarbons which require further laboratory and theoretical astrochemistry to resolve. This paper will also touch on related topics where laboratory and theoretical astrochemistry studies are needed to explain astrophysical observations, such as a possible absorption feature due to interstellar "diamonds" and the search for fullerenes in space.
Spectrochimica Acta A, Feb. 2001, in press. 33 pages including 11 postscript figures, AASTeX format. Full postscript paper also available at http://www.astronomy.ohio-state.edu/~sellgren/saa.html
References in corpus (3)
Cited by in corpus (13)
- The Dust Opacity of Star-Forming Galaxies
- Do the Infrared Emission Features Need Ultraviolet Excitation? The PAH Model in UV-Poor Reflection Nebulae
- Visible photodissociation spectroscopy of PAH cations and derivatives in the PIRENEA experiment
- The Mystery of Unidentified Infrared Emission Bands
- The C--H Stretching Features at 3.2--3.5 Micrometer of Polycyclic Aromatic Hydrocarbons with Aliphatic Sidegroups
- The 3.3 m PAH emission band of the Red Rectangle
- The Contribution of Evolved Stars to PAH Heating and Implications for Estimating Star Formation Rates
- The tight correlation of PAH and CO emission from z~0-4
- Estimating Molecular Gas Content in Galaxies from PAH Emission
- On the band-to-continuum intensity ratio in the infrared spectra of interstellar carbonaceous dust
- The Dust Content and Radiation Fields of Sample of Galaxies in the ELAIS-N1 Field
- Possible contribution of olefins and heteroatoms to the Unidentified Infrared Bands
- Long-wave mid-infrared cavity-enhanced frequency comb spectroscopy of cold, complex molecules