Beyond energy bounds: comparing Schrödinger eigenstates

Abstract

We derive eigenstate comparisons from ordered Schrödinger operators, extending energy bounds to overlaps, spatial distributions and nodes. For three form-ordered operators with discrete comparison ground states, suppose the upper ground-state energy lies in the lower operator's ground-state gap. Three comparison spectral values then bound all three squared ground-state overlaps and guarantee a simple discrete intermediate ground state. Related gap estimates control low-energy subspaces and individual excited-state overlaps under additional gap conditions. In one dimension and radially, a single crossing of the potential difference relative to the energy shift orders ground-state likelihood ratios and monotone observables; a nondecreasing difference suffices. The results cover asymmetric wells and shortened right Dirichlet walls, with coordinatewise comparisons for submodular reference potentials and coordinatewise nondecreasing perturbations. A two-sided Sturm argument orders corresponding internal nodes for nondecreasing potential differences, even between orthogonal one-dimensional excited states. For Yukawa ground states, Hulthén comparisons bound overlaps, radial moments and the density at the nucleus; the latter two-sided bounds hold for screening $0<\delta <2/\sqrt{6}$. Optimizing scaled Hulthén majorants gives a lower bound of approximately $1.13611$ for $n^2{\delta }_c(n,0)$, where ${\delta }_c(n,0)$ is the critical screening for the $n$th $s$-wave bound state. This bound is optimal within that two-parameter comparison family.

arXiv comment16 pages, 2 figures, 1 table. Core numerical code: https://github.com/Hronrad/ordered-schrodinger-eigenstates