Interactions and dynamics of metastable triplet-state helium dimer with Ne and Ar

Dibyendu Sardar; François Lique

paper

Interactions and dynamics of metastable triplet-state helium dimer with Ne and Ar

arXiv:2609.34713

Abstract

Helium dimer in its metastable triplet electronic state, He $_{2} (a^{3} Σ_{u}^{+})$ , is a promising candidate for direct laser cooling and precision measurements. Interactions and collisions involving He $_{2} (a^{3} Σ_{u}^{+})$ remain unexplored in ultracold and cold energy domains. Here, we present the first theoretical investigation of intermolecular interactions and collision dynamics of He $_{2} (a^{3} Σ_{u}^{+})$ +Ne van der Waals complex. For the ground electronic state, $X^{3} A^{'}$ , we employ a spin-restricted coupled cluster method with single, double, and noniterative triple excitations. The resulting interaction potential exhibits an extremely shallow well with a depth of 4.612 cm $^{- 1}$ . We construct a three-dimensional vibrationally averaged potential energy surface. Using this surface, we perform full close-coupling calculations including fine-structure levels of He $_{2} (a^{3} Σ_{u}^{+})$ to investigate collisional excitation and quenching induced by Ne. We analyze the low-energy scattering dynamics and model resonant features associated with quasi-bound states supported by interaction potential. Propensity rule for fine-structure conserving transitions is established. We additionally consider He $_{2}$ +Ar collisions and compare their energy dependence and resonance structure with those of He $_{2}$ +Ne. The He $_{2}$ +Ar system exhibits a richer resonance structure, highlighting the sensitivity of low-energy scattering to interaction potential and reduced mass. Calculated PES and scattering properties provide a reliable benchmark for description of He $_{2}$ +Ne van der Waals complex and may be useful for interpretation of future experimental spectra and collision measurements.