State-Dependent Diffusion and Spectra of Strongly Driven Thermal Atoms

Abstract

We propose a state-dependent diffusion model for strongly driven thermal-atom spectra. Starting from the trajectory-dependent internal-state evolution of individual atoms, we derive a closed spatial equation for the local density-matrix field using a velocity-moment expansion. Measurements of an ${}^{85}$Rb atomic-filter transmission spectrum agree well with the model up to a maximum Gaussian peak intensity of $1.27\times 10^3$ W/cm${}^2$, approaching six orders of magnitude above the ${}^{85}$Rb D2-line saturation intensity. Counterintuitively, the model reveals an anomalous optical-pumping pathway in which intense light transfers atoms from nominally dark states into bright states. Hyperfine Paschen--Back splitting selectively enhances this anomalous pathway while suppressing conventional optical pumping, allowing the filter to maintain approximately 97$\%$ transmission at the highest intensity studied. This work provides a framework for controlling strongly driven atomic ensembles and designing saturation-resistant atomic optical devices.

9 pages, 4 figures