Beyond capillary condensation: Shear-induced bridging transitions in patterned slits

Abstract

We study the equilibrium phase behavior of a fluid confined in a slit made from two patterned walls. Shearing the walls frustrates the fluid, due to a competition between capillary condensation and interface delocalization, forcing the formation of bridging phases with different pinning properties. This leads to an unusually rich phase diagram, displaying first-order and continuous phase transitions, depending sensitively on the slit width and shear. Generalized Kelvin equations determine the phase boundaries, while the bridging phases are characterized by large correlation lengths, predictions for which are tested using a microscopic density functional model.