Juno Microwave Observations Reveal Jupiter's Deep Alkali-Chlorine Relation

Abstract

The longest-wavelength channel of the Juno Microwave Radiometer (MWR) probes Jupiter's kilobar atmosphere through free electrons produced by sodium and potassium ionization. Under equilibrium chemistry the electron abundance is the small residual of the charge balance between alkali cations and the anions Cl- and HS-. Chlorine is not directly measurable in Jupiter's deep atmosphere because gaseous HCl is removed from the observable atmosphere by NH4Cl condensation, whereas sulfur has been measured by the Galileo probe. The MWR-derived electron measurement therefore constrains the alkali-to-chlorine ratio rather than the alkali abundance alone. We combine the MWR observations with equilibrium chemistry and microwave radiative transfer in a Bayesian framework, finding that the deep gas-phase elemental alkali-to-chlorine abundance ratio is (Na+K)/Cl = 0.05 over 0.3-5 times solar in chlorine, about 180 times below the protosolar ratio of 8.7. At 3 times solar chlorine, the inferred alkali metallicity is 1.6 x 10^-2 times solar (1 sigma: 1.2 x 10^-2 - 2.7 x 10^-2 times solar), while at low chlorine abundance HS- sets an alkali floor near 10^-3 times solar. The inferred gas-phase alkali abundance exceeds the ~10^-5 times solar threshold by more than two orders of magnitude and rules out the long-proposed global kilobar radiative zone. Because sodium and potassium are refractory whereas chlorine is volatile, the inferred ratio provides a new diagnostic of the rock-to-ice balance in the solids accreted by Jupiter. This compositional interpretation assumes equilibrium chemistry; if lofted mineral clouds instead control the electron abundance under disequilibrium conditions, the inferred alkali-chlorine relationship need not hold.

8 pages, 3 figures. Submitted to AAS Journals