Tilt-driven ferrielectricity in PbZrO${}_3$

Abstract

We reveal a tilt-driven mechanism for ferrielectricity in prototypical antiferroelectric PbZrO${}_3$. Specifically, introducing an additional octahedral tilt into the antiferroelectric $Pbam$ phase breaks the symmetry constraint that enforces equal antiparallel dipoles, converting the compensated ``$\uparrow \uparrow \downarrow \downarrow$'' nonpolar configuration into an uncompensated ``$\uparrow \uparrow \downarrow \downarrow$'' polar $Pmc{2}_1$ phase. First-principles calculations show that the $Pmc{2}_1$ phase becomes stabilized under lattice contraction and gains increasing free-energy advantage over competing phases at finite temperatures. Atomic-scale imaging directly confirms the presence of $Pmc{2}_1$-like structures in thin films and single crystals. This work identifies a symmetry-governed, kinetically easily accessible pathway to ferrielectricity and establishes a form of ``competitive'' improper ferroelectricity, with broad implications for antiferroelectrics.