Putting PASPT2 on a Firmer Basis

Abstract

The recently proposed partial-active-space (PAS) multi-state second-order perturbation theory (PASPT2) [Precis. Chem. 4, 997 (2026)] features connected amplitudes and a connected, closed intermediate Hamiltonian. Despite these hallmarks, PASPT2 (denoted as PASPT2H from now on) is not strictly size-extensive, as originally thought (and numerically confirmed), albeit strictly size-consistent. Nevertheless, PASPT2 is near-extensive for the states with major projections on the chosen PAS ${\mathcal{M}}_0$. This becomes more transparent upon introducing PASPT2X, a strictly size-extensive variant. Compared with the intruder-prone PASPT2X, the intruder-free PASPT2H merely neglects the second-order corrections that are important only for those states with major projections on the orthogonal complement ${\mathcal{R}}_X$ of ${\mathcal{M}}_0$ within the closed space ${\mathcal{M}}_X$ ($={\mathcal{M}}_0\oplus {\mathcal{R}}_X$); however, such states are not supported by the chosen finite one-particle basis set. The weak violation of size-extensivity is therefore numerically insignificant for the target states supported by ${\mathcal{M}}_0$, reinforcing the theoretical basis of PASPT2H.

3 figures,1 table