Microsecond-Scale Coherent Control of a Forbidden Clock Transition with Doppler-Free Multiphoton Excitations

Abstract

We demonstrate two Doppler-free (DF) excitation schemes for coherent manipulation of the ${}^1{S}_0-{}^3{P}_0$ clock transition in ${}^{88}$Sr that achieve microsecond-scale excitation times. The first approach uses three-photon excitation with distinct phase-coherent spectral components to couple the ground and clock states while canceling the first-order Doppler shift. The second approach is a sequential protocol that combines a single-photon excitation with a two-photon Raman excitation, reducing coherent clock transition manipulation times to below a microsecond. With both methods, we perform high-contrast Ramsey spectroscopy on thermal ensembles of $3\times 10^6$ atoms in free space. We observe three orders of magnitude suppression of Doppler dephasing compared to single-photon excitation, relaxing the need for tight confinement or ultra-low temperatures. These broadly applicable techniques enable fast, coherent manipulation of narrow-line transitions, with implications for optical atomic clocks, matter-wave interferometers, quantum-enhanced metrology, and quantum information processing.

19 pages, 6 figures