Orbital-selective band evolution and out-of-plane correlation in the FeGe-family kagome antiferromagnet ScFe${}_6$Ge${}_6$

Abstract

In strongly correlated materials such as high-temperature superconductors, the relation between charge density wave (CDW) order and magnetism remains an important unresolved problem. FeGe is the first kagome metal known to exhibit CDW order deep within an antiferromagnetic state, accompanied by an unconventional evolution of lattice symmetry. To elucidate the general conditions governing such spin-correlated CDW order, we investigate ScFe${}_6$Ge${}_6$, which lacks CDW order and therefore exhibits reduced involvement of charge degrees of freedom while retaining other properties of FeGe. Instead of a CDW order, ScFe${}_6$Ge${}_6$ undergoes a magnetic transition at $T^{\ast }$ = 195 K. Across this transition, angle-resolved photoemission and Raman spectroscopy reveal orbital-selective behavior confined to a single kagome Dirac band, together with electron-phonon and magnetoelastic coupling to an out-of-plane phonon mode. These results suggest that orbital-selective physics and out-of-plane correlations play enhanced roles in realizing spin-correlated CDW order in magnetic kagome metals.

11 pages, 4 figures