FNO-CCSDTQ(5)${}_{\hat{I}}›$ as an economical alternative for connected quintuple excitations contributions in coupled cluster thermochemistry

Abstract

Contributions from connected quintuple excitations in coupled cluster theory can reach the 0.5 kcal/mol range, important enough to matter in accurate computational thermochemistry, yet the very steep $\propto N^{12}$ CPU time scaling impedes routine evaluation. We show that for the differential contribution of quintuples, convergence of a frozen natural orbital (FNO) expansion with respect to the NO cutoff is rapid enough to make FNO-CCSDTQ(5)${}_{\hat{I}}›$ with cutoffs of 0.0025 or 0.001 viable alternatives. A naive extrapolation to zero cutoff from \{0.005,0.0025\} works surprisingly well as a low-cost option. Interestingly, FNO convergence is definitely slower for second-row than for first-row compounds.

Revised MS for Chemical Physics Letters (minor revision)

References in corpus (1)

• Toward an affordable density-based measure for the quality of a coupled cluster calculation

Cited by in corpus (1)

• A new open-shell CCSDTQ implementation and its application to the basis set convergence of post-CCSDT(Q) corrections in computational thermochemistry