Three-dimensional zigzag correlations in the van der Waals Kitaev magnet RuBr${}_3$

Abstract

Ruthenium trihalides Ru$X_3$ ($X$ = Cl, Br, I) provide a tunable platform for Kitaev magnetism in two-dimensional van der Waals materials. Despite their similar crystal structures and zigzag antiferromagnetic order, RuBr${}_3$ exhibits a higher Néel temperature ($T_N$) than RuCl${}_3$, suggesting their distinct proximity to the Kitaev quantum spin liquid phase. Using Ru $L_3$-edge resonant x-ray scattering, we show that, while the long-range zigzag order in RuBr${}_3$ disappears at $T_N$, the zigzag correlations that persist well above $T_N$ show a pronounced spectral weight redistribution along the interlayer direction. These results suggest that the enhanced interlayer magnetic interactions driven by the extended Br 4$p$ orbitals stabilize three-dimensional zigzag correlations in RuBr${}_3$.