Revisiting the symmetry and optical phonons of altermagnetic $\hat{I}\pm$-MnTe

Abstract

Using infrared (IR) and Raman spectroscopies combined with high-resolution x-ray diffraction, we address several controversial aspects of altermagnetic $\hat{I}\pm$-MnTe. We show that mechanical stress applied to crystals of this material causes a drastic broadening of Bragg peaks that conceals signatures of additional phases present in the sample. Indeed, spatially resolved Raman spectroscopy reveals that the modes around 175 cm${}^{-1}$ often reported in $\hat{I}\pm$-MnTe are not reproducible across different positions and samples and originate from the secondary phase of MnTe${}_2$. By combining spectroscopic probes with ab initio calculations, we establish the IR-active optical phonon of $\hat{I}\pm$-MnTe around 155 cm${}^{-1}$ ($E_{1u}$) and the Raman-active optical phonon around 100 cm${}^{-1}$ ($E_{2g}$) at room temperature. Two intense Raman modes around 120 and 140 cm${}^{-1}$ are shown to be intrinsic, even though they can not be assigned to $\hat{I}“$-point optical phonons. These modes couple to magnetic order in $\hat{I}\pm$-MnTe and also to the transient reflectivity resulting in coherent oscillations. Both 6-fold rotation symmetry and inversion symmetry are preserved in $\hat{I}\pm$-MnTe within our experimental resolution.

9 pages, 7 figures