Mystery of the 175 cm${}^{-1}$ Raman Mode in MnTe Altermagnet

Abstract

MnTe has recently attracted exceptional attention due to its well-established altermagnetism, prompting a thorough reexamination of its properties. In particular, it was found that a Raman-active excitation at ~175 cm${}^{-1}$, routinely assigned to the E2g phonon, is incompatible with this interpretation. It was further hypothesized that this mode is a "leakage", due to symmetry lowering, of an otherwise forbidden phonon. Here, using first-principles calculations, we decisively rule out this hypothesis and propose an alternative interpretation that the "mystery mode" is an electronic excitation, i.e., a plasmon, enabled by hole self-doping. The resolution of this mystery will require additional experiments and shed new light on the nature of electronic transport in MnTe.