Towards an understanding of dipole-dipole interactions in nonlocal media

Abstract

We commence our study with review of dispersion interactions in electrolytes. We then reflect on how background media change atom-atom excited-state systems. To highlight the impact of nonlocal media, such as salt solutions, we predict that a new contribution to the resonance interaction energy emerges in a form $\propto e^{-{\kappa }_{\mathrm{D}}\rho }/\rho$. Here ${\kappa }_{\mathrm{D}}$ is the Debye length and $\rho$ is the distance between the atoms. This contribution vanishes at zero temperature, where a new term proportional to $1/{\rho }^4$ (similar to free space) occurs. This new term is dampened by the electrolyte at large distances, causing it to decrease much faster, proportional to $1/{\rho }^7$. The long-range electrolyte-induced resonance interaction at finite temperature may, in addition to the dominating van der Waals attraction (which goes as $1/{\rho }^6$), take part in the molecular formation of biological fluids.

15 pages, 2 figures