Field-induced magnetic phase transition driven by a ground state level-crossing in CsErSe${}_2$

Abstract

We report a comprehensive study of the low-temperature magnetic properties of the insulating rare-earth triangular magnet CsErSe${}_2$. We uncover a field-induced level crossing at the crystal electric field (CEF) ground state, which gives rise to a first order phase transition as well as to distinctive magnetic properties. This crossing is identified by the accurate determination of the single-ion Hamiltonian, the reliability of which is substantially enhanced by field-dependent optical spectroscopy that directly tracks the Zeeman splittings of Kramers doublets. We also observe spontaneous antiferromagnetic ordering in CsErSe${}_2$ below $T_N\approx 110$ mK, and resolve the corresponding magnetic structure using elastic neutron scattering. We discuss how the rich magnetic behavior of CsErSe${}_2$ arises from the interplay of non-trivial field-dependent single-ion physics and spontaneous ordering, and highlight the implications of these results for understanding magnetic phenomena across a wide range of insulating rare-earth magnets.

12 pages, 7 figures, title and abstract updated. Major revision in the main text