Circular Dichroism without absorption in isolated chiral dielectric Mie particles

Abstract

We demonstrate that an effect phenomenologically analogous to circular dichroism can arise even for dielectric and isotropic chiral spherical particles. By analyzing the polarimetry of light scattered from a chiral, lossless microsphere illuminated with linearly polarized light, we show that the scattered light becomes nearly circularly polarized, exhibiting large, nonresonant values of the Stokes parameter $S_3$ for a broad range of visible frequencies. This phenomenon occurs only in the Mie regime, with the microsphere radius comparable to the wavelength, and provided that the scattered light is collected by a high-NA objective lens, including non-paraxial Fourier components. Altogether, our findings offer a theoretical framework and motivation for an experimental demonstration of a novel chiroptical effect with isolated dielectric particles, with potential applications in enantioselection and characterization of single microparticles, each and every one with its own chiral response.

22 pages, 5 figures