Quantum Filtering of Hydrogen Isotopes through Graphene
arXiv:2510.07461 · doi:10.1063/5.0286161
Abstract
Driven by the growing demand in the energy, medical, and industrial sectors, we investigate a hydrogen isotope separation technique that offers both a high separation factor and economic feasibility. Our findings reveal that filtering isotopes through two-dimensional graphene layers provides an exceptionally efficient quantum-mechanical method for isotope separation. Using a recently developed analytical pairwise potential between hydrogen isotopes and carbon atoms in graphene, we examine the classical trajectories of isotopes near the graphene layer, as well as the quantum-mechanical tunneling properties of isotopes through the graphene layer. Using various quantum-mechanical methods, we calculate both the isotope tunneling probabilities and the quantum-mechanical isotope sticking probabilities. Our study shows that quantum filtering through graphene layers can be an effective technique for enriching deuterium by separating it from protium.
arXiv comment10 pages with 11 figures
References in corpus (14)
- The electronic properties of graphene
- Proton transport through one atom thick crystals
- Anomalous Strength Characteristics of Tilt Grain Boundaries in Graphene
- Sieving hydrogen isotopes through two dimensional crystals
- Aqueous Proton Transfer Across Single Layer Graphene
- Melting temperature of graphene
- Scalable and efficient separation of hydrogen isotopes using graphene-based electrochemical pumping
- Raman Topography and Strain Uniformity of Large-Area Epitaxial Graphene
- Perfect proton selectivity in ion transport through two-dimensional crystals
- Density Functional Based Simulations of Proton Permeation of Graphene and Hexagonal Boron Nitride
- Ab initio simulations of the kinetic properties of the hydrogen monomer on graphene
- Transport of hydrogen isotopes through interlayer spacing in van der Waals crystals
- Dissipative Effects on Quantum Sticking
- Infrared Dynamics of Cold Atoms on Hot Graphene Membranes