Characterization of superconducting germanide and germanosilicide films of Pd, Pt, Rh and Ir formed by solid-phase epitaxy

Abstract

Facilitated by recent advances in strained Ge/SiGe quantum well (QW) growth technology, superconductor-semiconductor hybrid devices based on group IV materials have been developed, potentially augmenting the functionality of quantum circuits. The formation of highly transparent superconducting platinum germanosilicide (PtSiGe) contacts to Ge/SiGe heterostructures by solid-phase epitaxy between Pt and SiGe has recently been reported, although with a relatively low critical temperature $<1\mathrm{K}$. Here, we present a comparative study of the superconducting properties of Pt, Pd, Rh, and Ir germanides, along with an in-depth characterization of Ir(Si)Ge films formed by solid-phase epitaxy. For films fabricated under optimal epitaxy conditions, we report $T_{\mathrm{c}}=3.4\mathrm{K}$ ($2.6\mathrm{K}$ for IrGe (IrSiGe). High-resolution scanning transmission electron microscopy (HRSTEM) and energy-dispersive X-ray spectroscopy (EDX) reveal that Ir reacts with Ge substrates to form a polycrystalline IrGe layer with a sharp IrGe/Ge interface.

25 pages, 9 figures